
5
V. V.
V. V.
V.
Equipment required:Equipment required:
Equipment required:Equipment required:
Equipment required:
• Hanna HI 5315 Double Junction Reference Electrode
with HI 7072 Fill Solution for HI 4002.
• Hanna HI 4222 pH/ISE/mV meter or other suitable
ion or pH/mV meter. (Note: log/linear graph paper is
useful if an ISE (ion) meter is not available).
• Hanna HI 180 Magnetic Stirrer or equivalent with TFE
coated stirring bars (HI 731320). Note: isolate bea-
kers from stirrer motor heat by placing insulating
material such as foam or cork between them.
• Hanna HI 76404 Electrode Holder or equivalent.
• Plastic beakers (HI 740036P) or other suitable mea-
surement vessel.
VI. VI.
VI. VI.
VI.
Solutions RequiredSolutions Required
Solutions RequiredSolutions Required
Solutions Required
for Bromide Measurementsfor Bromide Measurements
for Bromide Measurementsfor Bromide Measurements
for Bromide Measurements
0.1 M Bromide Standard, 500 mL HI 4002-01
ISA, 500 mL HI 4000-00
For Molar solutions:
Using volumetric pipettes and glassware make serial dilu-
tions to approximately bracket the concentration of the
samples. Standards with concentrations < 10
-3
M should
be prepared daily.
Two mL of Hanna ISA for Halide electrodes (HI 4000-00)
should be added to 100 mL of sample or standard.
For ppm solutions:
Prepare 799 ppm bromide standard by diluting HI4002-
01: Pipette 100 mL standard to a 1 liter volumetric flask.
Add deionized water to volume. Using additional volumet-
ric pipettes and glassware make serial dilutions of this 799
ppm standard to approximately bracket the concentration
of the samples. Standards with concentrations < 80 ppm
should be prepared daily.
Two mL of Hanna ISA for Halide electrodes (HI 4000-00)
should be added to 100 mL of sample or standard.
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